What is a Mole in Chemistry?
The mole concept and stoichiometry are one of the many topics students usually encounter first while learning chemistry and there is a need to patiently introduce this to students.
What is a Mole in Chemistry? Mole is a term that has been well misconstrued by a lot of learners but sincerely it shouldn’t be so.
Before I go into detail in explaining this, I want to give few examples of what a mole of elements really implies.
When you have a bunch of keys, a school of fish, a team of players, and so on ….the same goes for a mole of elements or a mole of an atom of an element.
Mole Chemistry is simply a concept that talks about the application of mole in solving stoichiometry calculations.
What is the Definition of a Mole?
A mole is the amount that contains many elementary particles are there are 12 grams in carbon 12.
Hold on, no need to be confused that 12 grams of carbon have many elementary particles of carbon?
A glance at the periodic table gives us some more clarity on the atomic mass of elements.
To understand this better, just recall that the atomic mass of carbon is 12 but you can confirm this from the table. it means that I mole of carbon contains the atomic mass of carbon.
Carbon is arbitrarily used here as the reference for us to note that 1 mole of an element contains the atomic mass of the element.
How big is the Mole?
This question is raised because we humans use weight and mass and we want to relate the mole to these.
Actually, a mole is neither a unit of weight nor a unit of mass.
1000 moles of any substance will have the same number of elementary particles; we use both grams and moles in chemistry. A mole is simply a “building block” used to describe very large or small numbers. One gram is equal to one mole.
However, a mole of a substance can be related to mass, particles {Avogadro’s number} and even volume.
let me say this, a mole does not have a specific weight but depends on the substance of reference.
Mole and Mass Relationship
One mole of an atom of an element = atomic mass of the atom of an element
One mole of a molecule = molecular mass of the molecule
Mole and Avogadro’s number relationship
One mole of a substance – Avogadro’s number
Note =Avogadro’s number = 6.02 X 1023 atoms
This value 6.0 x 1023 is equally called the Avogadro’s constant.
Mole and volume relationship
One mole of a gas = molar volume
Molar volume is the volume of one mole of a gas at STP.
Note molar volume =22.4 dm23
The Mole concept
People also do ask questions like how many grams are in one mole of water or how many moles are in 1 liter of a substance.
The various questions can only be solved using the mole concept, the mole concept provides a simple way of solving calculations involving mole.
I will talk about the whole mole concept in future articles.
The mole concept is the foundation stone of chemistry since it helps to make calculations relating to the number of substances involved in any reaction. One mole of any substance has 6.0 x 1023 molecules or atoms or elementary particles in it.
learning to do some simple tasks involving mole chemiatry would be great as we have littered in all olevel chemistry calculations involving mole in Chemistry
10 Mole Concept Calculations
Example 1
What is the mass of 2.2 moles of Carbon?
Solution
Recall
1 dozen of eggs = 12,…it is constant
so also
1 mole of carbon = 12g {from periodic table}
Example 2
How many grams of water are there in 3 moles of water?
solution
Recall that
1 mole of a molecule = molecular mass/ molar mass
1 mole of water = molar mass of water
To get the atomic mass of element, use periodic table
So from periodic table, H =1, O=16
Molar mass of Water H2O = 1 X2 +16 = 18g/mol
Therefore 1 mole of water = 18g
3 moles = 3 x 18 = 54g
Example 3
How many moles are there in 200 of Calcium trioxo carbonate IV {CaCO3}
Solution
we use equivalence calculation that we have been using for the other ones
1 mole of CaCO3 = 100g
How?
From periodic table Ca =40, C=12, O-16
CaCO3= 40+12+16x 3= 40+12+48= 100g
Therefore 1 mole of CaCO3 = 100g
x moles = 200g
x moles = 1 mole x 200g / 100g = 2 moles
Example 4
What is the volume of 3.5 moles of carbon IV oxide?
Solution
Recall that 1 mole of a gas = molar volume
So 1 mole of CO2 = Molar volume
1 mole of CO2 = 22.4 dm3
3.5 moles of CO2 = x
x = 3.5 X 22.4 =78.4 dm3
Example 5
How many particles are there in 0.5 moles of sodium?
Solution
1 mole of Na = 6.02 x 10 >23 atoms
0.5 moles of Na = x
x = 0.5 x 6.02 x 1023/1 = 3.01 x 1023 atoms
Example 6
How many atoms are there in 20g of Calcium?
Solution
1 mole of Ca = 40g = 6.02 x 1023 atoms
20g = x
x = 20g x 6.02 x 1023/ 40g
x = 3.01 x 1023 atoms
Example 7
Consider this equation, N2 + 3H2 à 2NH3
How many moles of ammonia would be produced by 4 moles of hydrogen combining with nitrogen?
Solution
Background statement from the balanced equation
3 moles of Hydrogen yield 2 moles of ammonia
There 4 moles of hydrogen yields ……..
By equivalence calculations
If 3 moles of H2 = 2 moles of NH3
Then 4 moles of H2 = x
X = 4 x 2 /3 = 2.67 moles of NH3
Example 8
Consider the equation shown below;
CH4 + 2O2 –> CO2 + 2H2O
If 3.3 moles of methane burns completely in oxygen, Calculate the volume of carbon iv oxide evolved.
Solution
From balanced equation
Background statements
1 mole of CH4 = 1 mole of CO2
3.3 moles of CH4 = X
X = 3.3 X1 /1 = 3.3 moles of CO2
But the examiner asked for the volume of CO2?
Convert the mole to volume
I mole of CO2 = 22.4 dm3
3.3 moles of CO2 = x
X = 3.3 x 22.4dm3
X =73.92dm3
Example 9
What mass of Magnesium chloride would be produced by the reaction of 4.2 moles of magnesium with hydrochloric acid?
Mg + 2HCl –> MgCl2 + H2
Solution
Background statement from the balanced equation
1 mole of Mg =1 mole of MgCl2
4.2 moles of Mg à x
X = 4.2 x1 /1 = 4.2 moles of MgCl2
But we are asked for the mass of MgCl2?
So convert mole to mass
I mole of MgCl2 = 95g
4.2 moles of MgCl2 = x
X = 4.2 x 95 = 399g of MgCl2
Example 10
Consider the equation; 2SO2 + O2 à 2SO2
How many moles of sulfur iv oxide will produce 4 moles of sulfur vi oxide?
Solution
Background statement from the balanced equation
2 moles of SO2 = 2 moles of SO3
x moles = 4 moles
x = 2 x 4 /2 = 4 moles of SO2
So I believe we have been able to answer the question of what is a mole in Chemistry. However, the mole concept leads straight to the stoichiometry calculations.